Plasma Surface Activation

Plasma surface activation is effective at altering the surface of a polymer by attaching polar or functional groups to it. Many polymers, in particular polyolefins such as polyethylene and polypropylene, are chemically inert and cannot bond easily to other materials, displaying poor adhesion with inks, paint and glues. The reason for this is the absence of polar and reactive functional groups in their structure.

Plasma surface activation renders many polymers receptive to bonding agents and coatings. Oxygen is usually used as the process gas, however, many plasma activations can also be carried out with just ambient air. Parts remain active for a few minutes up to several months, depending on the particular material that has been plasma treated. Polypropylene, for example, can still be reprocessed several weeks after treatment.

How plasma surface activation works

UV radiation and active oxygen species from the plasma break up separating agents, silicones and oils from the surface. These are pumped away by the vacuum system. Active oxygen species (radicals) from the plasma bind to active surface sites all over the material, creating a surface that is highly ‘active’ to bonding agents.

Before Plasma Treatment
During plasma treatment
After Plasma Treatment

Plasma surface activation treatment is suitable for e.g.:

  • General Plastics and rubber
  • medical plastics
  • consumer electronics plastics
  • automotive components
  • aerospace components

PLASMA SURFACE ACTIVATION TESTS

The effects upon a plasma-treated activated surface are readily seen during subsequent product processing steps but there are a number of formal test methods that demonstrate the results too.

Contact angle measurement tests

Untreated surface
Plasma treated surface

Above left: The water naturally beads on an untreated metallic surface but spreads out (has lower contact angle) on a plasma-treated and activated surface in the image to the right.

Dyne inks surface energy test

Dyne test inks indicate a specific level of surface energy. The top line in the image above showing low surface energy, and a poor ability to bond the bottom displaying a clear improvement in surface energy and additionally adhesive and hydrophilic properties.

Grid Cut Tests

Untreated surface
Plasma treated surface

Grid test cut methods (DIN EN ISO 2409) clearly demonstrate the enhanced bonding (right image) to plasma activated surfaces after treatment.